Brooklyn Beckham & Nicola Peltz
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One of the first couples to hit the carpet, Beckham and the Transformers: Age of Extinction actress arrived in coordinated Valentino looks and shared a sweet smooch on the steps.
Adrien Brody & Georgina Chapman
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The French Dispatch actor and the designer, who made their relationship red carpet official at the Tribecca Film Festical in June, were all smiles as they posed for photos together.
Naomi Osaka & Cordae
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The tennis star, who is a co-chair for this year's gala, made a statement with her dramatic updo alongside her musician boyfriend.
Chance the Rapper & Kirsten Corley
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Dressed by stylist Law Roach in Ralph Lauren, the "No Problem" rapper and his wife paid homage to their native Chicago with his custom-made jacket.
Ben Affleck & Jennifer Lopez
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Fresh off their major Venice Film Festival moment, the couple met up inside the gala after Lopez walked the carpet.
James Corden & Julia Carey
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The Late Late Show host kept things classic in a black tux from Gucci alongside his wife, who dazzled in a metallic dress.
Serena Williams & Alexis Ohanian
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If this feathered cape isn't a grand slam, we don't know what is. The tennis star arrived in an ombré, feathered pink cape and a silver Gucci jumpsuit, while her husband kept things simple in a black Gucci tux and a coordinating silver bowtie.
Kit Harington & Rose Leslie
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The Game of Thrones alumni gave a nod to Old Hollywood glamour on the carpet.
Ayesha & Stephen Curry
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The Currys served up a matching metallic moment, with the professional basketball player coordinating his jacket's accents to his wife's silver and gold dress.
A$AP Rocky & Rihanna
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The last to arrive, the musicians made it worth the wait, turning heads in their complementary comforter coats.
Claire Danes & Hugh Dancy
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The actors went bridal-esque, with Danes wearing a white strapless dress and Dancy a black tux.
Shawn Mendes & Camila Cabello
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We'll "Never Be the Same" after seeing these ab-baring Michael Kors ensembles.
Alicia Keys & Swizz Beatz
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The "Girl on Fire" singer and her record producer husband arrived in coordinating black and white 'fits.
Pharrell Williams & Helen Lasichanh
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The rapper and his wife took us to the Wild West in their matching Chanel looks.
Taika Waititi & Rita Ora
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The singer sparkled in a Prada set alongside her director beau.
Justin & Hailey Bieber
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The Biebers arrived in style, with Justin wearing a suit from his own line, Maison Drew (Drew House) and his wife in a black Saint Laurent gown.